Title
Ten steps modeling of electrolysis processes by using neural networks
Abstract
Neural networks have been developed to model the electrolysis of wastes polluted with phenolic compounds, including phenol, 4-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, 4-nitrophenol and 2,4-dinitrophenol. They enable the prediction the Chemical Oxygen Demand of a treated waste as a function of the initial characteristics (pollutant concentration, pH), operation conditions (temperature, current density) and current charge passed. A consistent set of experimental data was obtained by electrochemical oxidation with conductive diamond electrodes, used to treat synthetic aqueous wastes. Several modeling strategies based on simple and stacked neural networks, with different transfer functions into the hidden and output layers, have been considered to obtain a good accuracy of the model. Global errors during the training stage were under 3% and those of the validation stage were under 4%, demonstrating that the neural network based technique is appropriate for modeling the system. The generalization capability of the neural networks was also tested in realistic conditions where Chemical Oxygen Demand was predicted with errors around 5%. Therefore, the developed neural models can be used in industry to determine the required treatment period, to obtain the discharge limits in batch electrolysis processes, and it is a first step in the development of process control strategies. The ten step methodology was applied to the neural network based process modeling.
Year
DOI
Venue
2010
10.1016/j.envsoft.2009.07.012
Environmental Modelling and Software
Keywords
Field
DocType
neural network,stacked neural networks,batch electrolysis process,developed neural model,chemical oxygen demand,ten step modeling,modeling strategy,step methodology,process modeling,current density,current charge,wastewater,process control strategy,transfer function,operant conditioning,process model,process control
Process engineering,Electrolysis,Hydrology,Computer science,Electrical conductor,Process modeling,Transfer function,Process control,Artificial neural network,Chemical oxygen demand,Environmental engineering
Journal
Volume
Issue
ISSN
25
1
Environmental Modelling and Software
Citations 
PageRank 
References 
12
1.31
4
Authors
5
Name
Order
Citations
PageRank
C. G. Piuleac1121.31
M. A. Rodrigo2212.07
P. Cañizares3121.31
Silvia Curteanu4636.26
C. Sáez5121.31