Name
Abstract | ||
|---|---|---|
The coupling between different molecular degrees of freedom plays a decisive role in many quantum phenomena, including electron transfer and energy redistribution. Here, we demonstrate a quantum-mechanical time-dependent simulation to explore how a vibrational motion in a molecule can be affected via the rotation-vibration coupling. Our simulations show that a slow (compared to the vibrational period) rotational excitation leads to a smooth increase in the bond length whereas a fast rotational excitation leads to a non-stationary vibrational motion. |
Year | Venue | Keywords |
|---|---|---|
2015 | 2015 5th Australian Control Conference (AUCC) | nonstationary vibrational motion,fast rotational excitation,bond length,slow rotational excitation,rotation-vibration coupling,quantum-mechanical time-dependent simulation,energy redistribution,electron transfer,molecular degrees of freedom,pure rotational excitations,molecular vibrational motion manipulation |
Field | DocType | Citations |
Macroscopic quantum phenomena,Coupling,Atomic physics,Rotational–vibrational spectroscopy,Vibrational partition function,Bond length,Electron transfer,Excitation,Stationary state,Physics | Conference | 0 |
PageRank | References | Authors |
0.34 | 0 | 2 |
Name | Order | Citations | PageRank |
|---|---|---|---|
| chuancun shu | 1 | 2 | 1.28 |
| niels engholm henriksen | 2 | 0 | 0.34 |