Title
Mechanism of Electrochemical Delamination of Two-Dimensional Materials from Their Native Substrates by Bubbling
Abstract
A capacitor-based circuit model is proposed to explain the electrochemical delamination of two-dimensional materials from their native substrates where produced gas bubbles squeeze into the interface. The delamination is actually the electric breakdown of the capacitor formed between the solution and substrate. To facilitate the procedure, the backside of the ubstrate has to be shielded so that the capacitor breakdown voltage can be reached. The screening effect can be induced either by nonreactive ions around the electrode or, more effectively, by an undetachable insulator. This mechanism serves as a guideline for the surface science and applications involving the bubbling delamination.
Year
DOI
Venue
2015
10.3390/s151229888
SENSORS
Keywords
Field
DocType
graphene,chemical vapor deposition,electrochemical bubbling transfer
Analytical chemistry,Capacitor,Graphene,Screening effect,Breakdown voltage,Engineering,Insulator (electricity),Electrode,Delamination,Chemical vapor deposition
Journal
Volume
Issue
ISSN
15
12.0
1424-8220
Citations 
PageRank 
References 
0
0.34
0
Authors
7
Name
Order
Citations
PageRank
Sun, J.110.96
xing fan200.34
Weiling Guo311.39
lihui liu400.34
xin liu500.34
jun deng600.34
chen xu701.01