Title
Metrics and Energy Landscapes in Irreversible Thermodynamics
Abstract
We describe how several metrics are possible in thermodynamic state space but that only one, Weinhold's, has achieved widespread use. Lengths calculated based on this metric have been used to bound dissipation in finite-time (irreversible) processes be they continuous or discrete, and described in the energy picture or the entropy picture. Examples are provided from thermodynamics of heat conversion processes as well as chemical reactions. Even losses in economics can be bounded using a thermodynamic type metric. An essential foundation for the metric is a complete equation of state including all extensive variables of the system; examples are given. Finally, the second law of thermodynamics imposes convexity on any equation of state, be it analytical or empirical.
Year
DOI
Venue
2015
10.3390/e17096304
ENTROPY
Keywords
DocType
Volume
finite-time thermodynamics,metric,bound,energy landscape,convexity
Journal
17
Issue
ISSN
Citations 
9
1099-4300
0
PageRank 
References 
Authors
0.34
0
1
Name
Order
Citations
PageRank
Bjarne Andresen142.52