Title
Retrieval Accuracy of HCHO Vertical Column Density from Ground-Based Direct-Sun Measurement and First HCHO Column Measurement Using Pandora.
Abstract
In the present study, we investigate the effects of signal to noise (SNR), slit function (FWHM), and aerosol optical depth (AOD) on the accuracy of formaldehyde (HCHO) vertical column density (HCHOVCD) using the ground-based direct-sun synthetic radiance based on differential optical absorption spectroscopy (DOAS). We found that the effect of SNR on HCHO retrieval accuracy is larger than those of FWHM and AOD. When SNR = 650 (1300), FWHM = 0.6, and AOD = 0.2, the absolute percentage difference (APD) between the true HCHOVCD values and those retrieved ranges from 54 (30%) to 5% (1%) for the HCHOVCD of 5.0 x 10(15) and 1.1 x 10(17) molecules cm(-2), respectively. Interestingly, the maximum AOD effect on the HCHO accuracy was found for the HCHOVCD of 3.0 x 10(16) molecules cm(-2). In addition, we carried out the first ground-based direct-sun measurements in the ultraviolet (UV) wavelength range to retrieve the HCHOVCD using Pandora in Seoul. The HCHOVCD was low at 12:00 p.m. local time (LT) in all seasons, whereas it was high in the morning (10:00 a.m. LT) and late afternoon (4:00 p.m. LT), except in winter. The maximum HCHOVCD values were 2.68 x 10(16), 3.19 x 10(16), 2.00 x 10(16), and 1.63 x 10(16) molecules cm(-2) at 10:00 a.m. LT in spring, 10:00 a.m. LT in summer, 1:00 p.m. LT in autumn, and 9:00 a.m. LT in winter, respectively. The minimum values of Pandora HCHOVCD were 1.63 x 10(16), 2.23 x 10(16), 1.26 x 10(16), and 0.82 x 10(16) molecules cm(-2) at around 1:45 p.m. LT in spring, summer, autumn, and winter, respectively. This seasonal pattern of high values in summer and low values in winter implies that photo-oxidation plays an important role in HCHO production. The correlation coefficient (R) between the monthly HCHOVCD values from Pandora and those from the Ozone Monitoring Instrument (OMI) is 0.61, and the slope is 1.25.
Year
DOI
Venue
2018
10.3390/rs10020173
REMOTE SENSING
Keywords
Field
DocType
trace gas,remote sensing,Pandora,direct-sun measurement,air pollution
Differential optical absorption spectroscopy,Correlation coefficient,Analytical chemistry,Optical depth,Trace gas,Remote sensing,Geology,Ozone Monitoring Instrument,Full width at half maximum,Radiance,Wavelength
Journal
Volume
Issue
ISSN
10
2
2072-4292
Citations 
PageRank 
References 
0
0.34
1
Authors
9
Name
Order
Citations
PageRank
Junsung Park111.46
Hanlim Lee2136.22
Jhoon Kim377.02
Jay R. Herman46417.02
Woogyung Kim500.34
Hyunkee Hong662.77
Wonei Choi712.81
Jiwon Yang800.34
Daewon Kim953.19