Title
Quantitative Analysis of Nutrient Elements in Soil Using Single and Double-Pulse Laser-Induced Breakdown Spectroscopy.
Abstract
Rapid detection of soil nutrient elements is beneficial to the evaluation of crop yield, and it's of great significance in agricultural production. The aim of this work was to compare the detection ability of single-pulse (SP) and collinear double-pulse (DP) laser-induced breakdown spectroscopy (LIBS) for soil nutrient elements and obtain an accurate and reliable method for rapid detection of soil nutrient elements. 63 soil samples were collected for SP and collinear DP signal acquisition, respectively. Macro-nutrients (K, Ca, Mg) and micro-nutrients (Fe, Mn, Na) were analyzed. Three main aspects of all elements were investigated, including spectral intensity, signal stability, and detection sensitivity. Signal-to-noise ratio (SNR) and relative standard deviation (RSD) of elemental spectra were applied to evaluate the stability of SP and collinear DP signals. In terms of detection sensitivity, the performance of chemometrics models (univariate and multivariate analysis models) and the limit of detection (LOD) of elements were analyzed, and the results indicated that the DP-LIBS technique coupled with PLSR could be an accurate and reliable method in the quantitative determination of soil nutrient elements.
Year
DOI
Venue
2018
10.3390/s18051526
SENSORS
Keywords
Field
DocType
soil,nutrient elements,laser-induced breakdown spectroscopy,single-pulse,double-pulse,chemometrics
Detection limit,Laser-induced breakdown spectroscopy,Radiant intensity,Analytical chemistry,Spectral line,Chemometrics,Quantitative analysis (chemistry),Engineering,Spectroscopy,Soil test
Journal
Volume
Issue
Citations 
18
5.0
0
PageRank 
References 
Authors
0.34
7
9
Name
Order
Citations
PageRank
Yong He148765.25
Xiaodan Liu222.16
Yangyang Lv300.34
Fei Liu4206.06
Jiyu Peng552.27
Tingting Shen631.98
Yun Zhao700.68
Yun Zhao800.68
Shaoming Luo901.69