Name
Abstract | ||
|---|---|---|
We present herein the synthesis and the characterization of a bis iminopyridyl ligand that's functionalized by two azobenzene unit and formulated as 4,4'-((1E,1'E)-(((1E,1'E)-(pyridine-2,6-diylbis(methanylylidene))bis (azanylylidene))bis(4,1-phenylene))bis(-diazene-2,1-diyl))bis(N,N-dimethylaniline) (L1). This ligand reacts with one equivalent of zinc chloride (ZnCl2) to afford the corresponding mononuclear Zn(II) metal complex formulated as [ZnL
<sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub>
Cl
<sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub>
]. Single crystals of this complex have been obtained and the X ray crystal structure analysis indicate complex [ZnL
<sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub>
Cl
<sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub>
], the tridentate ligand L1 is coordinated to the zinc(II) through its three nitrogen atoms. UV-Visible absorption spectroscopy shows the occurrence of intramolecular charge transfer (ICT) from the electron donating dimethylamino group to the iminopyridyl fragment and that this ICT band is red shifted in [ZnL
<sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">1</sub>
Cl
<sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub>
] complex due to the Lewis acidity of the zinc(II) metal cation. This results indicate that the resulting [ZnL
<sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">1</sub>
Cl
<sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub>
] complex is a valuable candidate for Nonlinear Optical (NLO) applications. |
Year | DOI | Venue |
|---|---|---|
2019 | 10.1109/ICTON.2019.8840333 | 2019 21st International Conference on Transparent Optical Networks (ICTON) |
Keywords | DocType | ISSN |
azobenzene,iminopyridyl ligand,zinc(II) complex,intramolecular charge transfer,crystal structure. | Conference | 2162-7339 |
ISBN | Citations | PageRank |
978-1-7281-2780-4 | 0 | 0.34 |
References | Authors | |
0 | 5 | |
Name | Order | Citations | PageRank |
|---|---|---|---|
| A. Ayadi | 1 | 0 | 0.34 |
| K. El Korchi | 2 | 0 | 0.34 |
| D. Guichaoua | 3 | 0 | 0.34 |
| S. Taboukhat | 4 | 0 | 0.34 |
| abdelkrim elghayoury | 5 | 0 | 2.37 |