Name
Abstract | ||
|---|---|---|
This paper presents a review of our original results obtained during the last decade. These results have been found theoretically for classical mass-action-law models of chemical kinetics and justified experimentally. In contrast with the traditional invariances, they relate to a special battery of kinetic experiments, not a single experiment. Two types of invariances are distinguished and described in detail: thermodynamic invariants, i.e., special combinations of kinetic dependences that yield the equilibrium constants, or simple functions of the equilibrium constants; and "mixed" kinetico-thermodynamic invariances, functions both of equilibrium constants and non-thermodynamic ratios of kinetic coefficients. |
Year | DOI | Venue |
|---|---|---|
2020 | 10.3390/e22030373 | ENTROPY |
Keywords | DocType | Volume |
invariant expression,two-step mechanism,scaled incremental conversion,conservatively perturbed equilibrium,linear complex mechanism,thermodynamic invariant | Journal | 22 |
Issue | ISSN | Citations |
3 | 1099-4300 | 0 |
PageRank | References | Authors |
0.34 | 0 | 4 |
Name | Order | Citations | PageRank |
|---|---|---|---|
| G. S. Yablonsky | 1 | 0 | 2.37 |
| Daniel Branco | 2 | 0 | 0.34 |
| G. B. Marin | 3 | 3 | 2.36 |
| Denis Constales | 4 | 3 | 4.16 |